For a binary mixture of ethanol and water, only one of the area fractions are required. An experiment was conducted for 4 different reflux ratios.
The area fraction of ethanol is reported from different tray locations corresponding (left to right): the feed, distillate, and bottom.
Ae
Ae = 4x3
0.2531 0.8103 0.0998
0.2477 0.8321 0.1176
0.2469 0.8400 0.1322
0.2457 0.8456 0.1500
The reflux ratios are:
R
R = 4x1
0.7489
1.3136
1.8355
2.3465
The units of the distillate and feed do not matter as long as they are consistent with each other. They are reported in mol/hr here.
D
D = 4x1
13.4285
11.0532
9.2384
7.9985
F
F = 4x1
41.9629
42.0177
42.0003
42.0018
Lastly, the feed temperatures were measured.
Tf
Tf = 4x1
26.8669
27.0785
26.9492
26.7919
When running the main script, the xy and Txy diagrams are outputted. The xy diagram is useful for visualizing the liquid-vapour equilibrium of ethanol. It is also used to step trays off of. The Txy diagram is used to determine the boiling or dew point of a inlet mixture.
For a subcooled liquid we expect q > 1 and q < 1 for a superheated mixture. The xy diagram at 1 atm is shown as follows:
%plot_xy()
The Txy diagram at 1 atm is shown as follows:
%plot_txy()
The McCabe Thiele diagram for a binary mixture of ethanol and water at 1 atm for a reflux of 0.75 could be drawn as follows:
main(Ae(1,:),Tf(1),R(1),F(1),D(1))